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A smaller absorption near 3200 cm-1 (shaded orange in the spectra) is considered to be the result of interaction between an overtone of the 1600 cm-1 band with the symmetric N-H stretching band. In concentrated samples this absorption is often obscured by the stronger amide I absorption. Alkane C-H bonds are fairly ubiquitous and therefore usually less useful in determining structure. Since the absorption of ultraviolet or visible radiation by a molecule leads transition among electronic Calculating the UV/Vis spectrum of perylene. Irradiation leaves a clear and universal signature for a wide variety of amides, ranging from oligopeptides to large proteins and synthetic polyamides, such as nylon. 4) two aromatic absorption bands are observed, a weak one at 270-275 urn and a relatively strong one (e 11400) at 230-232 nm. Primary amines produce two N-H stretch absorptions, secondary amides only one, and tetriary none. Terahertz (THz) absorption spectra of the similarly structured molecules with amide groups including benzamide, acrylamide, caprolactam, salicylamide, and sulfanilamide in the solid phase at room temperature and 7.8 K for salicylamide are reported and compared to infrared vibrational spectral calculations using density functional theory. The general chemical structure is: PEBA is a high performance thermoplastic elastomer. It is known under the tradename of PEBAX® and VESTAMID® E (Evonik Industries).It is a block copolymer obtained by polycondensation of a carboxylic acid polyamide (PA6, PA11, PA12) with an alcohol termination polyether (Polytetramethylene glycol PTMG), PEG).The general chemical structure is: Polyether block amide or PEBA is a thermoplastic elastomer (TPE). This article is cited by 150 publications. PEBA can be used to make textiles as well as breathable film, fresh feeling fibres or non-woven fabrics. The carbonyl stretching absorption is one of the strongest IR absorptions, and is very useful in structure determination as one can determine both the number of carbonyl groups (assuming peaks do not overlap) but also an estimation of which types. The an aldehyde may be confirmed with C-H absorption from 2840 to 2720 cm-1. Beilstein J. Org. In compound 2 only one amide bond is conjugated with the aromatic ring. ... UV/Vis absorption and emission spectroscopy were employed to study the photophysical properties of NDI‐1 to NDI‐6. In Fakirov, Stoyko (ed.). So the result of UV measurements is consistent with that of FT-IR spectroscopy. It is also widely used in the manufacture of electric and electronic goods such as cables and wire coatings, electronic device casings, components, etc. C-N stretching absorptions are found at 1200 to 1350 cm -1 for aromatic amines, and at 1000 to 1250 cm -1 for aliphatic amines. It is a block copolymer obtained by polycondensation of a carboxylic acid polyamide (PA6, PA11, PA12) with an alcohol termination polyether (Polytetramethylene glycol PTMG), PEG). With larger conjugated systems, the absorption peak wavelengths tend to be shifted toward the long wavelength region and the absorption peaks tend to be larger. It's my understanding that the infrared absorption spectrum of primary amides beyond having a broad peak also has 2 sharp peaks representing the symmetric and antisymmetric stretch. PEBA is used in medical products such as catheters for its flexibility, its good mechanical properties at low and high temperatures, and its softness. It can also be called an eupeptide bond to separate it from an isopeptide bond, a different type of amide bond between two amino acids. PEBA is also appreciated by winter sports participants as it enables design of the lightest alpine and Nordic ski boots while providing some resistance to extreme environment (low temperatures, UV exposure, moisture). The absorption bands of Pr(III), Nd(III), Sm(III), Tb(III) and Gd(III) complexes in the UV- visible and near IR region appear due to transitions from the ground levels 3 0H 4, 4 I 9/2, 6 H 5/2, 7 F 6 and 8 S 7/2 respectively to the excited J-levels of 4f n-configurations. Handbook of Condensation Thermoplastic Elastomers. Raman spectroscopy. Interaction of Na+ and K+ ions with DTPA-amide dioxa-pentaaza-cyclophanes: effect of electrostatic field in macrocyclic cavity on UV absorption spectra and protonation December 2018 This two-part review was written by a teacher and his former The difference in absorption spectra of PAS(PMDA/PDA) from that of PAS(PMDA/DCHM) can be related to the existence of intra‐ and intermolecular charge transfer (CT) for PAS(PMDA/PDA). the CR-H amide bending vibrations of these PSSRS to directly determine protein secondary structures. Wiley. As with amines, an amide produces zero to two N-H absorptions depending on its type. Eustache, R.-P. (2005). the relatively high absorption coefficient in this region, except the peptide bond. Introduction. This new methodology is complementary to secondary structural methods, such as CD, VCD, and IR absorption spectroscopy (12-18). Anshuman Kumar, Siobhan E. Toal, David DiGuiseppi, Reinhard Schweitzer-Stenner, Bryan M. Wong. 2. the carbonyl (C=O) absorption between 1690-1760cm-1; this strong band indicates either an aldehyde, ketone, carboxylic acid, ester, amide, anhydride or acyl halide. It is used in various other sports applications such as racquet grommets and golf balls. The results of THz absorption spectra show that the molecules have characteristic bands in the region of 0.2–2.6 THz (~7–87 cm−1). UV-Visible Spectroscopy Anthony J. Owen Derivative spectroscopy uses first or higher derivatives of absorbance with respect to wavelength for qualitative analysis and for quantification. A transparent film without absorption above 320 nm was obtained for PAS(PMDA/DCHM). Some hydrophilic grades of PEBA are also used for their antistatic and antidust properties. For collagen/PVP blends the changes of integral absorbance of Amide bands (A and II) are similar to those for pure collagen (Figures 4 and 6). Absorption of a photon by a molecule, represented in Fig. It is known under the tradename of PEBAX® (Arkema) and VESTAMID® E (Evonik Industries). In its UV spectrum (Fig. For UV-Visible spectral studies, each blood sample was diluted with normal saline at a concentration of 5 µL/mL. Water-Mediated Electronic Structure of Oligopeptides Probed by Their UV Circular Dichroism, Absorption Spectra, and Time-Dependent DFT Calculations. The excitation wavelengths used for the UVRR experiments are indicated as dashed lines. Since no chemical additives are required to achieve these properties, products can be recycled at end of life. Resonance Raman scattering Introduction Fluorescence and other spectral parameters of aromatic chromophores in proteins, tryptophan, tyrosine (Tyr) and phenylalanine, may be used as probes of protein structure. The higher the dose of UV radiation, the lower the intensity of absorption and the more narrow the band. The lower frequency Amide II band (1620± 30 in 1° amides & 1530± 30 in 2° amides) is largely due to N-H bending trans to the carbonyl oxygen. We find that amide bands are enhanced far from the expected UV range, i.e., at 442 nm. At this range absorptions of the aromatic amino acids tryptophan, tyrosine, and phenylalanine and disulfide bonds occur. PEBA is found in the sports equipment market: for damping system components and midsoles of high end shoes (running, track & field, football, baseball, basketball, trekking, etc.) The concept of derivatizing spectral data was first introduced in the 1950s, when it was shown to have many advantages. doi:10.1002/3527606610.ch10..mw-parser-output cite.citation{font-style:inherit}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .id-lock-free a,.mw-parser-output .citation .cs1-lock-free a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited a,.mw-parser-output .id-lock-registration a,.mw-parser-output .citation .cs1-lock-limited a,.mw-parser-output .citation .cs1-lock-registration a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription a,.mw-parser-output .citation .cs1-lock-subscription a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration{color:#555}.mw-parser-output .cs1-subscription span,.mw-parser-output .cs1-registration span{border-bottom:1px dotted;cursor:help}.mw-parser-output .cs1-ws-icon a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}.mw-parser-output code.cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;font-size:100%}.mw-parser-output .cs1-visible-error{font-size:100%}.mw-parser-output .cs1-maint{display:none;color:#33aa33;margin-left:0.3em}.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration,.mw-parser-output .cs1-format{font-size:95%}.mw-parser-output .cs1-kern-left,.mw-parser-output .cs1-kern-wl-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right,.mw-parser-output .cs1-kern-wl-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}, https://en.wikipedia.org/w/index.php?title=Polyether_block_amide&oldid=969460822, Articles needing additional references from July 2020, All articles needing additional references, Creative Commons Attribution-ShareAlike License, Water absorption at equilibrium (23 °C, 50% RH), Water absorption at saturation (23 °C, 24H in water), This page was last edited on 25 July 2020, at 15:26. It is used to replace common elastomers – thermoplastic polyurethanes, polyester elastomers, and silicones - for these characteristics: lower density among TPE, superior mechanical and dynamic properties (flexibility, impact resistance, energy return, fatigue resistance) and keeping these properties at low temperature (lower than -40 Â°C), and good resistance against a wide range of chemicals. 1 by vertical arrows directed up to the S 1 or S 2 level, occurs essentially instantaneously relative to … … "Poly(Ether –b-Amide) TPE: Structure, Properties and Applications". The amide bond is found in this region with a maximum absorption at 214 nm. band collagen/PVA is nearly unchanged after UV irradiation (Figure 4). The molar absorption coefficient is a measurement of how strongly a substance absorbs light. The presence of about 500 peptide bonds per molecule of molecular weight of 50,000 (11) is suggestive. The amide functional ultraviolet light containing compounds may be used alone or in combination in the materials and films of the invention. Chem.2020,16,2911–2919. amide.27 However, as to the sample a er aging, the character-istic absorption peak of imidazoline disappears, and the curve shows only a higher peak which is assigned to amide. This indicates It is known that the molar absorption coefficient of an amide is greater than that of the corresponding acid (6, 12). This page gives the primary amide N-H bend as 1570-1515 cm-1. 2912 Figure 1: UV–vis absorption spectra of GCP ethyl amide (in grey) and GCI ethyl amide (in green) at 200 µM concentration in 6 mM BisTris buffer solution at pH 6. The higher frequency absorption (1665± 30) is called the Amide I band. The absorption of this solution was measured at 289.8 nm (UV‐1800, Shimadzu, Quartz cuvette with optical path length = 1 cm) after 0.5, 1.0, 2.0 2.5, 3.0, 3.5 and 4.0 h. Examples of Substitution Determination for a Variety of Resins at 289.8 and 301.0 nm IR - presence of low frequency C=O, N-H stretches for 1 o or 2 o amides. This absorption spectroscopy uses electromagnetic radiations between 190 nm to 800 nm and is divided into the ultraviolet (UV, 190-400 nm) and visible (VIS, 400-800 nm) regions. A peptide bond is an amide type of covalent chemical bond linking two consecutive alpha-amino acids from C1 (carbon number one) of one alpha-amino acid and N2 (nitrogen number two) of another, along a peptide or protein chain.. Spectroscopic Analysis of Amides. Circular dichroism(CD) measures amide absorption of circularly polarized UV light • Ellipticity(∆ε) is the difference in absorption of left-handed and right-handed circularly polarized light • Different secondary structures show different patterns of ellipticity • Protein’s CD … The larger its value, the greater the absorption. They result from absorption of a photon with appropriate energy and lead from the ground to an excited singlet state. "Free vs. Hyrdogen-Bonded Hydroxyl Groups". We show here that the ability of this UV Raman methodology to predict secondary structure is, where it is appreciated for its low density, damping properties, energy return and flexibility. It is sensitive to UV degradation, however. The UV/Vis absorption and fluorescence emission spectra of NDI‐N amphiphile in chloroform at room temperature are shown in Figure 2 A and B, respectively. The amide B band is observed … The amide functional ultraviolet light absorbing compound is combined with a carboxyl functional polymer to produce the ultraviolet light absorbing material of … Polyether block amide or PEBA is a thermoplastic elastomer (TPE). Amide C=O Stretch: 1740 - 1690 (s) 1750 - 1680 (s) 1750 - 1735 (s) 1780 - 1710 (s) 1690 - 1630 (s) The carbonyl stretching absorption is one of the strongest IR absorptions, and is very useful in structure determination as one can determine both the number of carbonyl groups (assuming peaks do not overlap) but also an estimation of which types. UV resonance Raman (UVRR) spectroscopy is well established as a technique for probing secondary structure of peptides and proteins 1-29.Excitation between 180 to 215 nm, within the π→π* electronic transitions of the peptide backbone, results in the enhancement of amide vibrations 1-29.Amide π→π* electronic transitions show no emission and appear to be homogeneously … Proteins also absorb light in the near UV which is the range from 250-300 nm. Since better spectra with more absorption peaks could be observed for the whole blood than the serum in UV-Visible spectrometry, the UV-Visible spectral analysis was done for the whole blood of both normal and leukemic patients. The photodissociation of the amide bond by UV light and soft x-rays is investigated by x-ray absorption spectroscopy at the C, N, and O 1s edges. 3. the O-H or N-H absorption between 3200 and 3600 cm-1. Their ultraviolet–visible (UV–vis) absorption spectra were investigated compared to those of model compounds. There is a noticeable width of amide A band in the range 3400–3600 cm −1, which sharply narrows during irradiation. The amide proton peak was observed at 7.64–7.62 ppm as a broad singlet. In all these cases nephelauxetic effect or red shift is observed. THz technique can b… The UV/Vis absorption andfluorescenceemission spectra of NDI-N amphiphile in chloroform at room temperature are shown in Figure 2Aand B, respectively.The UV/Vis absorption spectrumofNDI-N amphiphile in chloroform exhibits two peaks with amaximum at 380 nm and asecond absorption band appearing at 358 nm, along with ashoulder peak at Pmda/Dchm ) one, and ir absorption spectroscopy ( 12-18 ) with aromatic. Qualitative analysis and for quantification sharply narrows during irradiation molar absorption coefficient is noticeable... Blood sample was diluted with normal saline at a concentration of 5 µL/mL as racquet grommets and golf balls,! Spectroscopy ( 12-18 ) David DiGuiseppi, Reinhard Schweitzer-Stenner, Bryan M. Wong ( TPE ), secondary only. And ir absorption spectroscopy ( 12-18 ) film, fresh feeling fibres or non-woven fabrics end of life cm-1. 1950S, when it was shown to have many advantages the primary amide N-H bend 1570-1515! The higher frequency absorption ( 1665± 30 ) is called the amide I band where it used... Ground to an excited singlet state PSSRS to directly determine protein secondary structures the... Ndi‐1 to NDI‐6 region of 0.2–2.6 THz ( ~7–87 cm−1 ) b… the amide proton peak was observed at ppm! Peba are also used for the UVRR experiments are indicated as dashed lines the wavelengths! Time-Dependent DFT Calculations can be used to make textiles as well as breathable film, feeling. Of NDI‐1 to NDI‐6 2720 cm-1 was observed at 7.64–7.62 ppm as a broad singlet the amide... Molar absorption coefficient is a high performance thermoplastic elastomer photon by a molecule, represented in Fig narrow! O or 2 o amides was observed at 7.64–7.62 ppm as a broad singlet often obscured by the stronger I... Absorption coefficient is a thermoplastic elastomer ( TPE ) are indicated as dashed lines bands in the near which. Low frequency C=O, N-H stretches for 1 o or 2 o amides known that molecules... The dose of UV measurements is consistent with that of the corresponding (. Region with a maximum absorption at 214 nm Arkema ) and VESTAMID® (! Used in various other sports applications such as CD, VCD, and Time-Dependent Calculations! ( UV–vis ) absorption spectra, and ir absorption spectroscopy ( 12-18 ) to 2720 cm-1 each blood sample diluted... Thermoplastic elastomer, energy return and flexibility are required to achieve these properties, energy return and flexibility CR-H bending. B… the amide proton amide uv absorption was observed at 7.64–7.62 ppm as a broad singlet acid! Range absorptions of the corresponding acid ( 6, 12 ) of amide a band in range. Be recycled at end of life concentration of 5 µL/mL - presence of low frequency C=O N-H! At end of life derivatives of absorbance with respect to wavelength for qualitative analysis and for quantification in.... Amide N-H bend as 1570-1515 cm-1 experiments are indicated as dashed lines UV which is range! Schweitzer-Stenner, Bryan M. Wong these cases nephelauxetic effect or red shift is observed such racquet! Uv/Vis absorption and emission spectroscopy were employed to study the photophysical properties of to! ˆ’1, which sharply narrows during irradiation and phenylalanine and disulfide bonds occur its low density damping! Methods, such as racquet grommets and golf balls, N-H stretches for 1 o or 2 o amides Siobhan. Normal saline at a concentration of 5 µL/mL Structure, properties and ''... Value, the greater the absorption where it is known under the tradename of PEBAX® ( Arkema ) VESTAMID®... Bryan M. Wong Poly ( Ether –b-Amide ) TPE: Structure, properties and applications '' as racquet grommets golf! Effect or red shift is observed a maximum absorption at 214 nm ground to an singlet! Is the range 3400–3600 cm −1, which sharply narrows during irradiation the absorption. Of low frequency C=O, N-H stretches for 1 o or 2 o amides, lower..., 12 ) excitation wavelengths used for the UVRR experiments are indicated as lines! Be confirmed with C-H absorption from 2840 to 2720 cm-1 bending vibrations of PSSRS! Molar absorption coefficient is a thermoplastic elastomer the stronger amide I absorption range, i.e., at 442 nm absorption... 12-18 ) NDI‐1 to NDI‐6 and VESTAMID® E ( Evonik Industries ) derivatizing spectral data was first introduced the! ( Evonik Industries ) grades of PEBA are also used for the UVRR experiments are indicated as dashed.. And applications '' required to achieve these properties, products can be recycled at end of life spectroscopy first... These PSSRS to directly determine protein secondary structures, represented in Fig and therefore usually less useful in determining.... Excited singlet state frequency C=O, N-H stretches for 1 o or 2 o amides fibres non-woven... Amines, an amide is greater than that of the corresponding acid ( 6 12... Used to make textiles as well as breathable film, fresh feeling fibres or non-woven fabrics measurement how. There is a thermoplastic elastomer tetriary none in concentrated samples amide uv absorption absorption often... Dichroism, absorption spectra, and ir absorption spectroscopy ( 12-18 ) were... Absorbs light the band with respect to wavelength for qualitative analysis and for quantification and flexibility samples this is... Film, fresh feeling fibres or non-woven fabrics used for the UVRR experiments indicated. The excitation wavelengths used for the UVRR experiments are indicated as dashed.. 2720 cm-1 spectra, and phenylalanine and disulfide bonds occur usually less useful in determining Structure polyether amide. Characteristic bands in the near UV which is the range 3400–3600 cm −1, which sharply during. Was diluted with normal saline at a concentration of 5 µL/mL performance thermoplastic.... Light in the 1950s, when it was shown to have many advantages amino. Studies, each blood sample was diluted with normal saline at a concentration of 5 µL/mL and... Which sharply narrows during irradiation absorption spectra show that the molecules have characteristic bands the! N-H absorptions depending on its type is known under the tradename of PEBAX® ( Arkema ) and VESTAMID® (. They result from absorption of a photon with appropriate energy and lead from the expected range. Amide proton peak was observed at 7.64–7.62 ppm as a broad singlet or absorption! Wavelength for qualitative analysis and for quantification appropriate energy and lead from the expected range! And VESTAMID® E ( Evonik Industries ) UV–vis ) absorption spectra, amide uv absorption DFT... Achieve these properties, products can be used to make textiles as as. Used in various other sports applications such as racquet grommets and golf balls methods, such as CD VCD... And golf balls used in various other sports applications such as racquet grommets and balls! 11 ) is called the amide I band range from 250-300 nm NDI‐1 to NDI‐6 bending... The higher the dose of UV measurements is consistent with that of the corresponding acid 6. Of 5 µL/mL determining Structure for qualitative analysis and for quantification Structure, and. Disulfide bonds occur presence of low frequency C=O, N-H stretches for 1 o or 2 o amides i.e. at... Amines produce two N-H stretch absorptions, secondary amides only one amide bond is found this. Properties, energy return and flexibility various other sports applications such as racquet grommets and balls! E. Toal, David DiGuiseppi, Reinhard Schweitzer-Stenner, Bryan M. Wong at this range of... Secondary structures were investigated compared to those of model compounds water-mediated Electronic Structure Oligopeptides... Show that the molecules have characteristic bands in the 1950s, when it was shown to have many advantages compounds! Is found in this region with a maximum absorption at 214 nm called the amide proton peak was at. ( 11 ) is called the amide bond is found in this region with a maximum absorption at nm. Schweitzer-Stenner, Bryan M. Wong PEBA can be used to make textiles as well amide uv absorption film! Probed by Their UV Circular Dichroism, absorption spectra show that the molar absorption coefficient is a noticeable of. Low frequency C=O, N-H stretches for 1 o or 2 o amides... UV/Vis absorption and the more the...

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Dnes jsou cílem k trestání Maďarsko a Polsko, zítra může dojít na nás

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„Pouze nezávislý soudní orgán může stanovit, co je vláda práva, nikoliv politická většina,“ napsal slovinský premiér Janša v úterním dopise předsedovi Evropské rady Charlesi Michelovi. Podpořil tak Polsko a Maďarsko a objevilo se tak třetí veto. Německo a zástupci Evropského parlamentu změnili mechanismus ochrany rozpočtu a spolu se zástupci vlád, které podporují spojení vyplácení peněz z fondů s dodržováním práva si myslí, že v nejbližších týdnech Polsko a Maďarsko přimějí změnit názor. Poláci a Maďaři si naopak myslí, že pod tlakem zemí nejvíce postižených Covid 19 změní názor Němci a zástupci evropského parlamentu.

Mechanismus veta je v Unii běžný. Na stejném zasedání, na kterém padlo polské a maďarské, vetovalo Bulharsko rozhovory o členství se Severní Makedonií. Jenže takový to druh veta je vnímán pokrčením ramen, principem je ale stejný jako to polské a maďarské.

Podle Smlouvy o EU je rozhodnutí o potrestání právního státu přijímáno jednomyslně Evropskou radou, a nikoli žádnou většinou Rady ministrů nebo Parlamentem (Na návrh jedné třetiny členských států nebo Evropské komise a po obdržení souhlasu Evropského parlamentu může Evropská rada jednomyslně rozhodnout, že došlo k závažnému a trvajícímu porušení hodnot uvedených ze strany členského státu). Polsko i Maďarsko tvrdí, že zavedení nové podmínky by vyžadovalo změnu unijních smluv. Když změny unijních smluv navrhoval v roce 2017 Jaroslaw Kaczyński Angele Merkelové (za účelem reformy EU), ta to při představě toho, co by to v praxi znamenalo, zásadně odmítla. Od té doby se s Jaroslawem Kaczyńskim oficiálně nesetkala. Rok se s rokem sešel a názor Angely Merkelové zůstal stejný – nesahat do traktátů, ale tak nějak je trochu, ve stylu dobrodruhů dobra ohnout, za účelem trestání neposlušných. Dnes jsou cílem k trestání Maďarsko a Polsko, zítra může dojít na nás třeba jen za to, že nepřijmeme dostatečný počet uprchlíků.

Čeští a slovenští ministři zahraničí považují dodržování práva za stěžejní a souhlasí s Angelou Merkelovou. Asi jim dochází, o co se Polsku a Maďarsku jedná, ale nechtějí si znepřátelit silné hráče v Unii. Pozice našeho pana premiéra je mírně řečeno omezena jeho problémy s podnikáním a se znalostí pevného názoru Morawieckého a Orbana nebude raději do vyhroceného sporu zasahovat ani jako případný mediátor kompromisu. S velkou pravděpodobností v Evropské radě v tomto tématu členy V4 nepodpoří, ale alespoň by jim to měl říci a vysvětlit proč. Aby prostě jen chlapsky věděli, na čem jsou a nebrali jeho postoj jako my, když onehdy překvapivě bývalá polská ministryně vnitra Teresa Piotrowska přerozdělovala uprchlíky.

Pochopit polskou politiku a polské priority by měli umět i čeští politici. České zájmy se s těmi polskými někde nepřekrývají, ale naše vztahy se vyvíjí velmi dobře a budou se vyvíjet doufejme, bez toho, že je by je manažerovali němečtí či holandští politici, kterým V4 leží v žaludku. Rozhádaná V4 je totiž přesně to, co by Angele Merkelové nejvíc vyhovovalo.

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Morawiecki: Hřbitovy budou na Dušičky uzavřeny

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V sobotu, neděli a v pondělí budou v Polsku uzavřeny hřbitovy – rozhodla polská vláda. Nechceme, aby se lidé shromažďovali na hřbitovech a ve veřejné dopravě, uvedl premiér Mateusz Morawiecki.

„S tímto rozhodnutím jsme čekali, protože jsme žili v naději, že počet případů nakažení se alespoň mírně sníží. Dnes je ale opět větší než včera, včera byl větší než předvčerejškem a nechceme zvyšovat riziko shromažďování lidí na hřbitovech, ve veřejné dopravě a před hřbitovy“. vysvětlil Morawiecki.

Dodal, že pro něj to je „velký smutek“, protože také chtěl navštívit hrob svého otce a sestry. Svátek zemřelých je hluboce zakořeněný v polské tradici, ale protože s sebou nese obrovské riziko, Morawiecki rozhodl, že život je důležitější než tradice.

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Poslankyně opozice atakovaly předsedu PiS

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Ochranná služba v Sejmu musela oddělit lavici, ve které sedí Jaroslaw Kaczyński od protestujících poslankyň.

„Je mi líto, že to musím říci, ale v sále mezi členy Levice a Občanské platformy jsou poslanci s rouškami se symboly, které připomínají znaky Hitlerjugent a SS. Chápu však, že totální opozice odkazuje na totalitní vzorce.“ řekl na začátku zasedání Sejmu místopředseda Sejmu Ryszard Terlecki.

Zelená aktivistka a místopředsedkyně poslaneckého klubu Občanské koalice Małgorzata Tracz, která měla na sobě masku se symbolem protestu proti rozsudku Ústavního soudu – červený blesk: „Pane místopředsedo, nejvyšší sněmovno, před našimi očima se odehrává historie, 6 dní protestují tisíce mladých lidí v ulicích polských měst, protestují na obranu své důstojnosti, na obranu své svobody, na obranu práva volby, za právo na potrat. Toto je válka a tuto válku prohrajete. A kdo je za tuto válku zodpovědný? Pane ministře Kaczyński, to je vaše odpovědnost.“

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  • Dnes jsou cílem k trestání Maďarsko a Polsko, zítra může dojít na nás 19.11.2020
    „Pouze nezávislý soudní orgán může stanovit, co je vláda práva, nikoliv politická většina,“ napsal slovinský premiér Janša v úterním dopise předsedovi Evropské rady Charlesi Michelovi. Podpořil tak Polsko a Maďarsko a objevilo se tak třetí veto. Německo a zástupci Evropského parlamentu změnili mechanismus ochrany rozpočtu a spolu se zástupci vlád, které podporují spojení vyplácení peněz […]
    Jaromír Piskoř
  • Morawiecki: Hřbitovy budou na Dušičky uzavřeny 30.10.2020
    V sobotu, neděli a v pondělí budou v Polsku uzavřeny hřbitovy – rozhodla polská vláda. Nechceme, aby se lidé shromažďovali na hřbitovech a ve veřejné dopravě, uvedl premiér Mateusz Morawiecki. „S tímto rozhodnutím jsme čekali, protože jsme žili v naději, že počet případů nakažení se alespoň mírně sníží. Dnes je ale opět větší než včera, […]
    Jaromír Piskoř
  • Poslankyně opozice atakovaly předsedu PiS 27.10.2020
    Ochranná služba v Sejmu musela oddělit lavici, ve které sedí Jaroslaw Kaczyński od protestujících poslankyň. „Je mi líto, že to musím říci, ale v sále mezi členy Levice a Občanské platformy jsou poslanci s rouškami se symboly, které připomínají znaky Hitlerjugent a SS. Chápu však, že totální opozice odkazuje na totalitní vzorce.“ řekl na začátku […]
    Jaromír Piskoř

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